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Lithian ferrian enstatite with Li2O = 1.39 wt% and Fe2O3 7.54 wt% was synthesised in the (MgO–Li2O–FeO–SiO2–H2O) system at P = 0.3 GPa, T = 1,000°C, fO2 = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å3. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula M2(Mg0.59Fe 0.21 2+ Li0.20) M1(Mg0.74Fe 0.20 3+ Fe 0.06 2+ ) Si2O6. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe3+ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe3+ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe2+) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe3+, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe2+-Mg ordering process in octahedral sites.  相似文献   
44.
This paper examines the dynamics of innovation in low-carbon energy technologies distinguishing between research and development and technology diffusion as a response to alternative climate policies. We assess the implications of second-best policies that depart from the assumption of immediate and global participation and of full technology availability. The analysis highlights the heterogeneous effects of climate policy on different energy R&D programs and discusses the contribution of important determinants such as carbon price and policy stringency, policy credibility, policy and technological spillovers and absorptive capacity.  相似文献   
45.
The veracity of modeled air–sea interactions in the Indian Ocean during the South Asian summer monsoon is examined. Representative simulations of the twentieth century climate, produced by coupled general circulation models as part of the Intergovernmental Panel on Climate Change Fourth Assessment Report, are the analysis targets along with observational data. The analysis shows the presence of large systematic biases in coupled simulations of boreal summer precipitation, evaporation, and sea surface temperature (SST) in the Indian Ocean, often exceeding 50% of the climatological values. Many of the biases are pervasive, being common to most simulations. The representation of air–sea interactions is also compromised. Coupled models tend to emphasize local forcing in the Indian Ocean as reflected by their large precipitation–SST correlations, at odds with the weak links in observations which suggest the importance of non-local controls. The evaporation–SST correlations are also differently represented, indicating atmospheric control on SST in some models and SST control on evaporation in others. The Indian monsoon rainfall–SST links are also misrepresented: the former is essentially uncorrelated with antecedent and contemporaneous Indian Ocean SSTs in nature, but not so in most of the simulations. Overall, coupled models are found deficient in portraying local and non-local air–sea interactions in the Indian Ocean during boreal summer. In our opinion, current models cannot provide durable insights on regional climate feedbacks nor credible projections of regional hydroclimate variability and change, should these involve ocean–atmosphere interactions in the Indian basin.  相似文献   
46.
This paper warns against the risk of underestimating the costs—and the uncertainty about the costs—of achieving stringent stabilization targets. We argue that a straightforward review of integrated assessment models results produces biased estimates for the more ambitious climate objectives such as those compatible with the 2°C of the European Union and the G8. The magnitude and range of estimates are significantly reduced because only the most optimistic results are reported for such targets. We suggest a procedure that addresses this partiality. The results show highly variable costs for the most ambitious scenarios.  相似文献   
47.
Despite the growing concern about actual on-going climate change, there is little consensus on the scale and timing of actions needed to stabilise the concentrations of greenhouse gases. Many countries are unwilling to implement mitigation strategies, at least in the short term, and no agreement on an ambitious global stabilisation target has yet been reached. It is thus likely that international climate policies will be characterized by a high degree of uncertainty over the stringency of the climate objective, and that some countries might delay their participation to global action. What additional economic costs will this delay in the adoption of mitigation measures imply? What would the optimal short-term strategy be given the uncertainty surrounding the climate policy to come? Is there a hedging strategy that decision makers can adopt to cope with delayed action and uncertain targets? This paper addresses these questions by quantifying the economic implications of delaying mitigation action, and by computing the optimal abatement strategy in the presence of uncertainty about a global stabilisation target (which will be agreed upon in future climate negotiations). Results point to short-term inaction as the key determinant for the economic costs of ambitious climate policies. They also indicate that there is an effective hedging strategy that could minimise the cost of climate policy uncertainty over the global stabilisation target: a short-term moderate climate policy would be a good strategy to reduce the costs of delayed action and to cope with uncertainty about the outcome of future climate negotiations. By contrast, failing to curb emissions in the short term imposes rapidly increasing additional costs of compliance.  相似文献   
48.
Abstract– We detail the Kamil crater (Egypt) structure and refine the impact scenario, based on the geological and geophysical data collected during our first expedition in February 2010. Kamil Crater is a model for terrestrial small‐scale hypervelocity impact craters. It is an exceptionally well‐preserved, simple crater with a diameter of 45 m, depth of 10 m, and rayed pattern of bright ejecta. It occurs in a simple geological context: flat, rocky desert surface, and target rocks comprising subhorizontally layered sandstones. The high depth‐to‐diameter ratio of the transient crater, its concave, yet asymmetric, bottom, and the fact that Kamil Crater is not part of a crater field confirm that it formed by the impact of a single iron mass (or a tight cluster of fragments) that fragmented upon hypervelocity impact with the ground. The circular crater shape and asymmetries in ejecta and shrapnel distributions coherently indicate a direction of incidence from the NW and an impact angle of approximately 30 to 45°. Newly identified asymmetries, including the off‐center bottom of the transient crater floor downrange, maximum overturning of target rocks along the impact direction, and lower crater rim elevation downrange, may be diagnostic of oblique impacts in well‐preserved craters. Geomagnetic data reveal no buried individual impactor masses >100 kg and suggest that the total mass of the buried shrapnel >100 g is approximately 1050–1700 kg. Based on this mass value plus that of shrapnel >10 g identified earlier on the surface during systematic search, the new estimate of the minimum projectile mass is approximately 5 t.  相似文献   
49.
The Atacama Large Millimeter/Submillimeter Array (ALMA) is an international millimeter-wavelength radio telescope under construction in the Atacama Desert of northern Chile. ALMA will be situated on a high-altitude site at 5000 m elevation which provides excellent atmospheric transmission over the instrument wavelength range of 0.3 to 3 mm. ALMA will be comprised of two key observing components—a main array of up to sixty-four 12-m diameter antennas arranged in a multiple configurations ranging in size from 0.15 to ∼18 km, and a set of four 12-m and twelve 7-m antennas operating in a compact array ∼50 m in diameter (known as the Atacama Compact Array, or ACA), providing both interferometric and total-power astronomical information. High-sensitivity dual-polarization 8 GHz-bandwidth spectral-line and continuum measurements between all antennas will be available from two flexible digital correlators. At the shortest planned wavelength and largest configuration, the angular resolution of ALMA will be 0.005″. The instrument will use superconducting (SIS) mixers to provide the lowest possible receiver noise contribution, and special-purpose water vapor radiometers to assist in calibration of atmospheric phase distortions. A complex optical fiber network will transmit the digitized astronomical signals from the antennas to the correlators in the Array Operations Site Technical Building, and post-correlation to the lower-altitude Operations Support Facility where the array will be controlled, and initial construction and maintenance of the instrument will occur. ALMA Regional Centers in the US, Europe, Japan and Chile will provide the scientific portals for the use of ALMA; early science observations are expected in 2010, with full operations in 2012.  相似文献   
50.
Ice divide–dome behaviour is used for ice sheet mass balance studies and interpretation of ice core records. In order to characterize the historical behaviour (last 400 yr) of Dome C and Talos Dome (East Antarctica), ice velocities have been measured since 1996 using a GPS system, and the palaeo-spatial variability of snow accumulation has been surveyed using snow radar and firn cores. The snow accumulation distribution of both domes indicates distributions of accumulation that are non-symmetrical in relation to dome morphology. Changes in spatial distributions have been observed over the last few centuries, with a decrease in snow accumulation gradient along the wind direction at Talos Dome and a counter-clockwise rotation of accumulation distribution in the northern part of Dome C. Observations at Dome C reveal a significant increase in accumulation since the 1950s, which could correlate to altered snow accumulation patterns due to changes in snowfall trajectory. Snow accumulation mechanisms are different at the two domes: a wind-driven snow accumulation process operates at Talos Dome, whereas snowfall trajectory direction is the main factor at Dome C. Repeated GPS measurements made at Talos Dome have highlighted changes in ice velocity, with a deceleration in the NE portion, acceleration in the SW portion and migration of dome summit, which are apparently correlated with changes in accumulation distribution. The observed behaviour in accumulation and velocity indicates that even the most remote areas of East Antarctica have changed from a decadal to secular scale.  相似文献   
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